Mr. Smelly was ready. 
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Smart Cat respected Mr. Smelly, must of had a run in with him before.
I think most critters know what a 
can do, except some dogs. 
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Possibly wanting to avoid Pepe Le Pew’s affections.
Wow, that was a close one! The skunk even dug in and raised the tail in the ready position to see if kitty was a threat
Too bad kitty didn’t hiss or growl or run or do something stupid. Would’ve made for a better story and video And ongoing jokes for a while.