I think you’re asking a couple of different questions here, and I’ll start by saying that I don’t have any direct experience with Duo Cam Doorbell or any of Wyze’s lock products.
I don’t believe the new Wi-Fi Chime works that way. My understanding of Wi-Fi Chime is that it’s essentially an independent Wi-Fi device (which is why it can work with other Wyze cameras and doorbells and why Wyze plans to sell it separately at some point) that connects to your home LAN and communicates only via Wi-Fi. I believe Chime Pro included with Video Doorbell Pro does act as a gateway between your home router and the doorbell, but I don’t think the Wi-Fi Chime included with Duo Cam Doorbell does this.
You should already be able to do this whether the Wi-Fi Chime is installed or not, as long as your Duo Cam Doorbell has been setup correctly. If what you actually meant was remote access to your Lock Bolt that way, though, then that’s a different question entirely.