Thanks for the rules image, I see a problem in the Rules. You do not need to add the Turn Off action (image attached with arrows to what I am saying). The Rule is setup to turn on the bulbs or plugs at a certain time and then when the end time comes, they will turn off.
Basically, modify your Rules and remove the Off Action for everything where there is an On Action. In general your rule is telling your devices to go on and off at the same time when you have the actions setup the way they are.
Note: When using the Sunset or Sunrise as part of the start or end time, there is a 2 hour or so limitation. Not sure exactly when it kicks in. But to get around that, you would simply remove the end times from your rules. This will turn on your bulbs and plugs at the given time. Then setup another rule to turn the bulbs and plugs off at a given start time.
Basically doing this:
20 minutes before Sunset will be the start time and then the actions would be to turn on your devices.
Then
11:05 pm or 11:00 pm will be the star tune and then the action would be to turn off your devices.